That depends on whether you want to change the initial condition in a WACCM run with interactive chemistry, or change the the prescribed ozone in CAM or SC-WACCM.
Assuming you want to use CAM or SC-WACCM, look in the atmosphere namelist file (CaseDocs/atm_in) to find pointers to the prescribed_ozone_datapath and prescribed_ozone_file, such as:
prescribed_ozone_datapath = '/glade/p/cesmdata/cseg/inputdata/atm/cam/ozone_strataero'
prescribed_ozone_file = 'ozone_strataero_WACCM_L70_zm5day_18500101-20150103_CMIP6ensAvg_c180923.nc'
You can then copy this file to one with a different name, and then apply any scaling you want to the O3 variable. Then you need to point to your new file by adding two lines to user_nl_cam in your case directory in order to modify the namelist:
prescribed_ozone_datapath = '/path/to/file'
prescribed_ozone_file = 'ozone_x0.85_strataero_WACCM_L70_zm5day_18500101-20150103_CMIP6ensAvg_c20220416.nc'
Note, that this does not apply to the FW2000climo compset, since that is a WACCM compset with interactive chemistry. If you just want to change the initial condition in WACCM, look for ncdata in atm_in, and follow a similar procedure to copy it and scale O3.