Is there a reason why you aren't using WACCM6? WACCM5 was an intermediate stage. Although we do have this one WACCM5 compset in the release, I don't remember exactly why we released it, and I might need to do some investigating to understand what is in it.
In WACCM6, stratospheric aerosol injections are handled via the external forcing. In the namelist, this is a list of emissions files and corresponding species in the ext_frc_specifier. For example, below is the default list for the BWHIST compset.
If you want to do stratospheric SO2 injections, you would create a similar emissions file describing the region where you want SO2 emitted. You can also add a scale factor in front of the path to the emissions file, such as "4*" to multiply the emission rates by a factor of 4.
ext_frc_specifier = 'bc_a4 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_bc_a4_aircraft_vertical_1750-2015_0.9x1.25_c20170608.nc',
'NO2 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_NO2_aircraft_vertical_1750-2015_0.9x1.25_c20170608.nc',
'num_a1 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_num_so4_a1_anthro-ene_vertical_1750-2015_0.9x1.25_c20170616.nc',
'num_a1 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_num_a1_so4_contvolcano_vertical_850-5000_0.9x1.25_c20170724.nc',
'num_a2 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_num_a2_so4_contvolcano_vertical_850-5000_0.9x1.25_c20170724.nc',
'num_a4 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_num_bc_a4_aircraft_vertical_1750-2015_0.9x1.25_c20170608.nc',
'SO2 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_SO2_aircraft_vertical_1750-2015_0.9x1.25_c20170608.nc',
'SO2 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_SO2_contvolcano_vertical_850-5000_0.9x1.25_c20170724.nc',
'SO2 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/stratvolc/VolcanEESMv3.11_SO2_850-2016_Mscale_Zreduc_1deg_c180812.nc',
'so4_a1 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_so4_a1_anthro-ene_vertical_1750-2015_0.9x1.25_c20170616.nc',
'so4_a1 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_so4_a1_contvolcano_vertical_850-5000_0.9x1.25_c20170724.nc',
'so4_a2 -> /glade/p/cesmdata/cseg/inputdata/atm/cam/chem/emis/CMIP6_emissions_1750_2015/emissions-cmip6_so4_a2_contvolcano_vertical_850-5000_0.9x1.25_c20170724.nc'