And I would say that such a large value is possible in CLM5, although not common and generally where the PFT fractions are small within the gridcell.
These are max TLAI values from monthly history data from the CLM5 historical simulation (year 2010) reported in Lawrence et al. 2019:
(0) Max TLAI for NL Evergreen Boreal Tree:10.6109
(0) Max TLAI for NL Deciduous Boreal Tree:10.7108
(0) Max TLAI for BL Evergreen Tropical Tree:7.67813
(0) Max TLAI for BL Evergreen Temperate Tree:7.60654
(0) Max TLAI for BL Deciduous Tropical Tree:12.5318
(0) Max TLAI for BL Deciduous Temperate Tree:12.7937
(0) Max TLAI for BL Deciduous Boreal Tree:8.24843
(0) Max TLAI for BL Evergreen Shrub:6.11496
(0) Max TLAI for BL Deciduous Temperate Shrub:5.71172
(0) Max TLAI for BL Deciduous Boreal Shrub:11.8843
(0) Max TLAI for C3 arctic grass:18.5222
(0) Max TLAI for C3 non-arctic grass:22.8415
(0) Max TLAI for C4 grass:17.0945
(0) Max TLAI for C3 crop:21.5434
So, a large value is possible for several of the PFTS.